Why is My 12 Volt Battery Reading as 13 Volts?

All Lead acid batteries (Gel, AGM, Flooded, Drycell, etc) are made up of a series of 2.2 volt cells that are bridged together in series to reach their final desired voltage. For instance, a 6 volt battery will have 3 cells (3 x2.2= 6.6 volts), a 12 volt battery will have 6 cells (6 x2.2=13.2 volts) and so on.That 2.2 volts is the fully charged, straight off the charger number. The actual resting voltage, or the voltage a battery will settle at 12-24 hours after being removed from the charger, is closer to 2.1 volts per cell, or about 6.4 volts for a 6v battery, and 12.7 volts for a 12v battery. These numbers assume 100% healthy cells, and may vary a bit lower for older batteries.

Source: https://www.batterystuff.com